Effect of sulfur and oxygen on weld penetration of high. Austenitic stainless steels, sensitized during welding austenitic stainless steels, sensitized during welding katty11 petroleum. Gastungsten arc gta welds were done on low and highsulfur 304 and 316 heats using pure argon and argonoxygen shielding gases. Asymmetry in steel welds with dissimilar amounts of sulfur. Austenitic manganese steel contracts about fifty percent more than carbon steel, and that difference causes shrinkage stress, which. It replaces the conventional, austenitic stainless steels aisi 316 and 317, where their capabilities are pushed to their performance limits. Hot cracking is a welding problem that does not occur in pure metals but may. Austenitic stainless steels, sensitized during welding. One layer of 309 would not be enough to avoid producing an haz in the p11. Mechanical behavior of austenitic stainless steel weld. Selfpassivation of austenitic steel 316 l and its welded. The microstructure of type308 austenitic stainless steel weld metal containing gamma and delta and ferrite is shown. A w marshall and j c m farrar metrode products limited, uk keywords.
The parent metal of copper was observed with coarse alpha grains and by heataffected zone, and the grains were recrystallized due to heat generated in the interface of weld region. In austenitic welds dendritic structure is the most clear. Friction welding of austenitic stainless steel with copper. Three different electrode compositions were used to overlayweld austenitic manganese steel cast in the form of rail heads. Epa was used to identify the defect that occurs in the weld metal. How do it do to avoid welding cracks on manganese steel parts. Stress corrosion cracking of austenitic stainless steels by sulfur compounds has been investigated and the following results are obtaind. Embrittlement of austenitic stainless steel welds unt. The traditional way of displaying the austenitic stainless steels is to present 302 as a base. Additions of hydrogen and sulfur to filler metal 82 were also investigated and found to increase the susceptibility of the weld metal to ddc.
Cracking is always intergranular along the prior austenite grain boundaries fig. Although it is possible to weld austenitic stainless steels with traditionally high dilution processes, like submerged arc welding, parameter control is crucial to avoiding cracking. The martensitic 400 series of stainless steel is more challenging to laser weld than the austenitic and ferritic grades. Laser welding of stainless steels prima power laserdyne. Reliability of dissimilar metal welds subjected to sulfide. Table 4 mo segregation in weld metal weld metal bulk mo content, wt % dendrite core, wt% interdendritic region, wt% s31254 6. The values for austenitic base material are presented by point b in figure 6. Solidification cracking is a significant problem during the welding of austenitic stainless steels, particularly in fully austenitic and stabilized compositions. Exposure of austenitic stainless steel welds to elevated temperatures can lead to extensive changes in the microstructural features. For purposes of discussion, in welding there are three zones of principal concern. In austenitic stainless steel, the parent metal was observed with carbide particles and annealed twin boundaries, whereas in the heat affected zone, recrystallized. Ultrasonic testing of austenitic and dissimilar metal.
Metallurgical analysis of the weld metal microstructures revealed contrasting grain boundary characteristics. Stress corrosion cracking of austenitic stainless steels. Contribution of phosphorus and sulfur on hot cracking. Steel castings handbook supplement 7 welding of high. Microcracking can also be found both in the haz and within the weld metal. Welding research an investigation of ductility dip. Small variations in the concentration of surfactants, such as sulfur and oxygen, in stainless steels cause significant changes in the weld penetration and depthwidth dw ratio of the fusion zone.
Hot cracking susceptibility of austenitic stainless steels american. Nature and evolution of the fusion boundary in ferriticaustenitic dissimilar metal welds part 2. In the case of sulfur, it is possible to overcome the harmful effects of iron sulfides by preferentially forming manganese sulfide. It was reported to the malfunction investigation staff mis that uncoated low a1 loy steel filler metal had been inadvertently used to weld an austenitic stainless steel manifold. The welding parameters of atig and multipass tig welding of 316 ln have been given in table 4. Fusion boundary in ferriticaustenitic dissimilar weld metals, part 1 nucleation and growth. Charpy impact test was carried out and the composition of the weld metals was also analyzed. Hot cracking in austenitic stainless steel weld metals. Austenitic stainless steel weld metal exhibits a duplex microstructure consisting of a dispersion of high temperature deltaferrite in austenite. Request pdf solidification cracking in austenitic stainless steel welds. The test results show a similar yield strength, and a small difference on tensile strength for. Effect of ce addition to filler metal on microcracking.
Due to the lower melting temperature and lower thermal conductivity of austenitic base material, with respect to another two base materials, it was adopted that the share of austenitic steel in the weld metal is approximately 60 %. Mechanical behavior of allweldmetal specimens of 308l and 316l weld with and without microfissures was evaluated by standard and prestrain tensile testing. The shaeffler diagram above illustrates a carbon steel c. Suitable as a specifying tool and visual examination guide.
The ductilitydip cracking susceptibility in the reheated weld metal could be greatly improved by adding 0. Depends on the application, but proper after weld peening will help minimize or eliminate weld cracking or warping. Microstructure characterization of a duplex stainless. Solidification cracking in austenitic stainless steel.
When two steel plates containing dissimilar concentrations of sulfur are arc welded, a very unusual and strikingly asymmetric weld pool geometry forms. Cooling rate of weld metal, is the major one that controls the ferrite number in austenitic stainless steel weld deposits. After welding, clean the weld area to remove slag and heat tint to examine the weld integrity and also to allow the metal to be painted. Hot cracking in stainless steel welds is caused by lowmelting eutectics containing impurities such as s, p and alloy elements such as ti, nb. In addition to the differences in ductility and hardness, the difference in expansion characteristics of the base and weld metals should be considered before using such filler metal, particularly if the welded structure will be. Alloy 254smo 6mo f44 is a fully austenitic alloy containing 6% molybdenum and offering excellent corrosion resistance in a wide variety of aggressive, aqueous environments. Optical metallography revealed numerous very small microcracks on prior austenite grain boundaries throughout the weld metal fig. Weld metal characterized by cellulardendritic forms of crystallization that leads to formation of large columnar crystals and enrichment of interdendritic sections by low melting phase with sulfur.
It contains a high percentage of nickel and chromium, enhancing its ability to be formed and welded easily into any shape along with providing great strength and resistance to corrosion. Fabrication hydrogen cracking in sma 22%cr duplex stainless steel weld deposits may be avoided by maintaining a weld metal phase balance of less than 60% ferrite and a deposit hydrogen content of less than 18mlh 2 stp100g. Not only the weld should be tested, at least the heat affected zone left and right from the weld needs to be tested as well. Metallographic analysis was made on the weld metal and the heataffected zone as well. If possible, blast the weld area with iron free grit but if that is not possible, grind along the weld line to avoid dragging carbon steel contamination onto the stainless steel. Experimental data are presented on crack growth rates cgrs of the heat affected zone haz in types 304l and 304 ss weld specimens before and after they were irradiated to a fluence of 5.
If you click on a particular reference, it takes you to a page with a description, application, weld metal chemical analysis, as welded mechanical properties, current, sizes, and amperage. Welding variables and microfissuring in austenitic stainless steel. In testing austenitic welds, dissimilar metal welds and claddings, overlay and backlay structures it is usually possible to detect inclusions and crack shaped reflectors in the probes near surface zone. Weld cracking is a very complex phenomenon that can occur in both laser and resistance welding. Laminated sheet with color photograph showing degrees of coloration on the inside of an austenitic stainless steel tube with increasing amount of oxygen in the backing shielding gas. Chamovska et al selfpassivation of austenitic steel 316 l and zastita materijala 50 2009 broj 2 87 figure 3 cyclic voltammograms for electrochemical passivation of austenitic steel 316 l, basic material zone 3 in 1. Defects imperfections in welds reheat cracking twi. Metal 82, with filler metal 82 exhibiting a heattoheat variation in susceptibility. Investigation of aging heat treatment on microstructure. Structure formation and corrosion resistance of austenitic. Point a represents the anticipated composition of the weld metal, if it consists of a mixture of filler metal and 25% parent metal.
The abovementioned considerations for selfpassivation processes of austenitic. It is characterized by high strength, high ductility. This problem can be overcome if a higher alloyed filler is used, such as a 309l, which has a higher. Austenitic, 1682, 308l, 316l, cryogenic lateral expansion, hot cracking, stressrupture, dissimilar 1.
Sulphur segregation and intergranular microcracking in ferritic steel. Furthermore, due to the high cr content and the presence of alloying elements in the. Hydrogen cracking of ferriticaustenitic stainless steel. Study of austenitic stainless steel welded with low alloy.
Austenitic steel is a type of stainless steel that contains austenite. Crack growth tests were conducted under cycling loading and long hold time trapezoidal loading in. Temperbead welding, to produce an acceptable haz, always. Reliability of dissimilar metal welds subjected to sulfide stress cracking vol. When the arc is initially placed directly above the original interface of the two plates, the lower sulfur containing plate melts to a much greater extent than the higher sulfur plate and the maximum penetration does not occur. Welding of austenitic manganese steel austenitic manganese steel, called sll by m. Ferrite has relatively high solubility for sulfur, phosphorus, and silicon, thus precluding.
The wrc92 diagram can be used as a general guide to maintain. This diluted weld, according to the diagram, will contain martensite. For welding, the phosphorus and sulfur levels in these alloys are normally held. Amps, volts, travel speed and stepover distance must all be fully understood and precisely controlled. Duplex stainless steels have higher strength than austenitic stainless steels, higher toughness than ferritic stainless steels and good weldability 14. This microstructure can be considered intermediary between austenitic and ferritic stainless steels. The effect of ce addition on microcracking susceptibility in the multipass weld metal of alloy 690 was investigated in order to improve the microcracking susceptibility in it. So the selection of electrode diameters, arc length, amperages current and heat treatments are the controlling. The hot cracking susceptibility of extrahighpurity 25cr35ni stainless steel was. Solidification cracking in austenitic stainless steel welds request.